Xps characterization of nitrogen-doped carbon nano tubes pdf

Pdf spectroscopic characterization of ndoped singlewalled. Pdf synthesis of nitrogendoped carbon nanotubes using. Morphological, nitrogen doping characterization and. Either boron or nitrogendoped carbon nanotubes b or ncnts were incorporated in bulk heterojunction organic solar cells photoactive layer composed of poly3hexylthiophene p3ht. It is also expected that the modified electronic structure is different depending on the types of cn bonding configurations here, we report the atomicscale characterization of a nitrogendoped graphite surface by scanning tunnelling microscopy stm, scanning tunnelling spectroscopy sts, xps and. Nickel sulfide nanocrystals on nitrogendoped porous carbon. Electrocatalytic activities of the samples were characterized by. Perovskite oxide combined with nitrogendoped carbon. Surface modification of nitrogendoped carbon nanotubes byozone via atomic layer deposition andrew lushington, jian liu, yongji tang, ruying li, and xueliang suna department of mechanical and materials engineering, university of western ontario, london. Characterization of nitrogendoped carbon nanospheres using. A email protected nanocomposite was prepared by electroless deposition for the first time, which has a hihgly efficient electrocatalytic performance toward the hydrogen evolution reaction.

Raman characterization of nitrogen doped multiwalled carbon. Doped carbon nanotubes and their composites as oxygen reduction reaction electrocatalysts for low temperature fuel cells by drew higgins a thesis presented to the university of waterloo in fulfillment of the thesis requirement for the degree of master of applied science in. National creative research initiative center for multidimensional directed nanoscale. Nitrogen doped carbon nanotubes and their impact on the. In addition, the bonding configuration of nitrogen atoms in graphene layers was characterized by high resolution xps spectrum of n1s peak. Synthesis of nitrogendoped hollow carbon nanospheres for co. Synthesis of nitrogen doped hollow carbon spheres nhcss. Research article synthesis and characterization of silver. Nitrogendoped carbon nanotubes were prepared using ionic liquid as a precursor.

Metalfree and electrocatalytically active nitrogendoped. Nitrogen doped carbon nanotubes electrocatalytic activity morphologies fuel cells abstract nitrogen doped carbon nanotubes ncnts were synthesized by a single step chemical vapor deposition technique using either ferrocene or ironii phthalocyanine as catalyst and pyridine as the carbon and nitrogen precursor. The typical bamboolike nitrogen doped carbon nanotubes ncnts have been successfully synthesized via pyrolysis of melamine c 3 n 6 h 6. Synthesis and functionalization of nitrogendoped carbon. The present work focuses on nitrogen doped, defectinduced surfacemodified carbon nanotubes mnbcnt having the synergy of both the effects to improve the electrochemical performance of the nib. Raman characterization of nitrogen doped multiwalled carbon nanotubes. In situ characterization of gasphase nitrogencontaining precursors and their correlation to growth identifies hcn as the most active precursor for swnnt growth, analogous to c2h2 for singlewalled carbon nanotubes swnts. Synthesis and characterization of nitrogen doped carbon nanotubes.

Nitrogen doped carbon nanotubes ncnts have become a topic of increased. Vegadiaz, florentino lopezurias, ana laura elias, josue ortizmedina, emilio munozsandoval, mauricio terrones. Xps and raman characterization of singlewalled carbon nanotubes grown from pretreated fe 2o 3 nanoparticles placidus b amama1,4, dmitry zemlyanov1, b sundarakannan2, ram s katiyar2 and timothy s fisher1,3 4 1 birck nanotechnology center, purdue university, west lafayette, in 47907, usa. Initially, in situ nitrogen doped cnts were grown using a scalable, costeffective and green synthesis technique. Synthesis and characterization of nitrogen doped carbon nanotubes article pdf available in materials science forum 636 january 2010 with 433 reads how we measure reads. Tem images revealed that sno 2 and ceo 2 nanoparticles were uniformly attached on the surface of the nmwcnt. In the n 1s xray photoelectron spectroscopy xps spectrum fig. Characterization of nitrogendoped carbon nanotubes by atomic. Experimental section catalyst synthesis largediameter and fewwalled nitrogendoped carbon nano tubes ncnts were prepared by first mixing 24 mmol dicyandiamide with 6 mmol of one of the metal acetates mac x,m fe, co, ni or mn in 250 ml ethanol. This arises from the physical and chemical properties that are created when n is embedded in a cnt. In this work, cnts have been bombarded with low energy n ions. Spaceconfined synthesis of threedimensional boron nitrogen doped carbon nanotubes carbon nanosheets lineinwall hybrids and their electrochemical energy storage applications author links open overlay panel shan zhu a jiajun li a qingfeng li b chunnian he a c d enzuo liu a c fang he a chunsheng shi a naiqin zhao a c d.

Nitrogen doped carbon nanomaterials are known to exhibit good electrocatalytic activity for the oxygen reduction reaction orr. Synthesis of nitrogendoped carbon fibers cf has been proved to be one of the most promising oxygen reduction reaction orr catalysts which can replace the stateofart pt catalyst for nonnoble metalfree lightweight devices. Unique to the conventional template based lewis acidbase activation. Raman characterization of nitrogen doped multiwalled carbon nanotubes volume 772 s.

Nonenzymatic glucose detection using nitrogendoped diamond. In situ nitrogendoped, defectinduced carbon nanotubes as an. Nitrogendoped porous carbon monoliths from polyacrylonitrile. Nitrogendoped carbon nanotubes based on ionic liquid. Atomic scale characterization of nitrogendoped graphite. Nonenzymatic glucose detection using nitrogendoped diamondlike carbon electrodes modified with gold nanoclusters aiping liu1,2, erjia liu1, guocheng yang1, nay win khun1, and wenguang ma1 1school of mechanical and aerospace engineering, nanyang technological university, 50 nanyang avenue, singapore 639798, singapore.

Nitrogendoped carbon nanotubes as an excellent substrate. Nickel sulfide nanocrystals on nitrogendoped porous carbon nanotubes with highefficiency electrocatalysis for roomtemperature sodiumsulfur batteries. Rich nitrogendoped carbon on carbon nanotubes for high. The oxidation rate of swnts in air at elevated temperatures is correlated to the metal content of the sample. Pristine and fluorinated multiwalled carbon nanotubes mwcnts and singlewalled carbon nanotubes swcnts were characterized using energy dispersive xray spectra edx and xray photoelectron spectroscopy xps, respectively. And application as pd catalyst supports in a hydrogenation reaction. Synthesis, structure and properties of boron and nitrogen. The nitrogen doped hollow carbon spheres were prepared according to the literature method. Nitrogen doped carbon nanotubes and their impact on the oxygen reduction reaction in fuel cells zhu chen, drew higgins, zhongwei chen department of chemical engineering, waterloo institute of nanotechnology, waterloo institute for sustainable energy, university of waterloo. Xps, raman spectroscopy and thermogravimetric analysis tga. Xps and raman characterization of singlewalled carbon. Min chen a, wen wu a, yuyuan chen b, qingqing pan b, yongzhong chen c, zongfu zheng c, yanjie zheng b, liying huang b and shaohuang weng b a department of orthopedic surgery, fujian medical university union hospital, fuzhou 350001, china b. Raman characterization of nitrogen doped multiwalled.

Sincetheearly1990s,5,6 doping swcnts with nitrogen has been considered7 10 a viable option for tailoring their properties, while nitrogendoped. Nitrogen doped carbon nanotubes coated by atomic layer deposited sno 2 with controlled morphology and phase xiangbo meng, yu zhong, yifan sun, mohammad norouzi banis, ruying li, xueliang sun. In summary, we have developed a simple, scalable, cost. Xps characterization of nitrogendoped carbon nanotubes. These properties include modified chemical reactivity and modified conductivity and mechanical properties.

Nitrogen doped carbon nanotubes ncnts can be produced through five main methods. We report on the characterization of pecvd deposited nanotubes using auger electron spectroscopy aeswe. Coville1,3 1dstnrf centre of excellence in strong materials, wits 2050, south africa. In this work is presented a study of the shelf life of an ironimpregnated mgo femgo sample and an explanation of the effect of its aging on morphology and electroactivity of nitrogen doped carbon nanostructures prepared by using this catalyst at different ages. Characterization of nitrogen doped carbon nanotubes by atomic force microscopy, xray photoelectron spectroscopy and xray absorption near edge spectroscopy. Synthesis of nitrogendoped carbon nanotubes with layered. Xps and fesemstem surface characterization of activated. However, the analysis of xps datain particular the c 1s regioncan be complex, impeding a straightforward evaluation of the data. A fluorescent sensor constructed from nitrogendoped carbon. Synthesis and characterization of nitrogen doped carbon. Covillea, adstnrf centre of excellence in strong materials and the molecular sciences institute, school of chemistry, university of the witwatersrand, johannesburg, wits, 2050, south africa. Dubazane1,2, vincent marsicano2, nikiwe kunjuzwa1,3, neil j. Nitrogendoped carbon nanotube and graphene materials.

These assynthesized graphitic nanocups from chemical vapor deposition cvd method were stacked in a headtotail fashion held only through noncovalent interactions. Although nitrogendoped carbon nanotubes are a very poor hydrogen oxidation catalyst, as a support, it increases the catalytic performance of nickel nanoparticles by a factor of 33 mass activity or 21 exchange current density relative to unsupported nickel nanoparticles. Morant c1, torres r, jimenez i, sanz jm, elizalde e. To utilize carbon nanotubes cnts in various commercial and scientific applications, the graphene sheets that comprise cnt surfaces are often modified to tailor properties, such as dispersion. Perovskite oxide combined with nitrogendoped carbon nanotubes as bifunctional catalyst for rechargeable zincair batteries by vugar ismayilov a thesis presented to the university of waterloo in fulfillment of the thesis requirement for the degree of master of applied science in chemical engineering nanotechnology. Nitrogendoped carbon nanotubes cnxnts were prepared using a. We demonstrate see table i that indeed the shifts in vibrational frequencies. In search of the active site in nitrogendoped carbon. Xray photoelectron spectroscopy have been used to determine the binding configuration of the ndoped cnts. The physical and chemical properties were investigated using different spectroscopic techniques. Effects of synthesis parameters on the nitrogen content. In situ nitrogendoped, defectinduced carbon nanotubes as. Metalorganic frameworkderived bamboolike nitrogendoped graphene tubes as an active matrix for hybrid oxygenreduction electrocatalysts qing li, hengyu pan, drew higgins, ruiguo cao, guoqi zhang, haifeng lv. Jan 11, 2017 nitrogen doped porous activated carbon monoliths ndpacms have long been the most desirable materials for supercapacitors.

Characterization of nitrogen doped carbon nanospheres using electron magnetic resonance jonathan m. However, the structure of the orr active site and optimum content of nitrogen in the carbon lattice for orr activity remains unknown. We focus on the discussion of the inherent orr activity of nitrogendoped graphene and carbon nanotubes without additional metal catalysts. Electronic and optical properties of nitrogendoped.

Theory, synthesis and characterization of phosphorusnitrogen doped multiwalled carbon nanotubes. Structural and morphological control of aligned nitrogendoped. Multiwalled carbon nanotubes, both pure mwnts and nitrogen doped, were grown by chemical vapor deposition cvd. Nitrogen doped carbon nanotubes consist of many cupshaped graphitic compartments termed as nitrogen doped carbon nanotube cups ncncs. Nitrogendoped carbon nanotubepolymer nanocomposites towards thermoelectric applications, thermoelectrics for power generation a look at trends in the technology, sergey skipidarov and mikhail nikitin, intechopen, doi. Nickel supported on nitrogendoped carbon nanotubes as. The structure of an ideal infinitely long singlewalled carbon nanotube is that of a regular hexagonal lattice drawn on an infinite cylindrical surface, whose vertices are the positions of the carbon atoms. Nickel sulfide nanocrystals on nitrogendoped porous. Characterization of nitrogendoped carbon nanotubes by. Afm was also used to determine their morphology and mechanical properties.

Structural and morphological control of aligned nitrogen. Nitrogendoped carbon nanotubepolymer nanocomposites towards. Chemical and structural characterization of carbon nanotube. Electrocatalytic activity of nitrogen doped carbon. Herein, activated carbon ac and carbon nanotubes cnts were synthesised from potato peel waste ppw. Nitrogen doped carbon nanotubes and their composites as. Synthesis of nitrogendoped carbon nanotubes using injectionvertical chemical vapor deposition. Preparation and characterization of nitrogen doped reduced. Initially, in situ nitrogendoped cnts were grown using a scalable, costeffective and green synthesis technique. Chen jin a, tharamani chikka nagaiah b, wei xia a, bernd spliethoff c, shanshan wang c, michael bron b, wolfgang schuhmann b and martin muhler a a laboratory of industrial chemistry, ruhruniversity bochum, 44780, bochum, germany.

Production and characterisation of activated carbon and. Both the assynthesized graphite oxide go and the nitrogen doped reduced graphene oxide nrgo were characterized for their functional chemical bonds, surface morphology, chemical. Atomistic description of electron beam damage in nitrogen. Synthesis, characterization and application in solar cells by godfrey kamitha keru a thesis submitted to the school of chemistry and physics, college of agriculture, engineering and science, university of kwazulunatal, westville campus, for the award of the degree of doctor of philosophy. Metalorganic frameworkderived bamboolike nitrogendoped. The massive introduction and retention of nitrogen heteroatoms 12 at.

In 1this study, nitrogen doped reduced graphene oxide were synthesized from chemically produced graphite oxide. Sizecontrolled largediameter and fewwalled carbon nanotube. Based on the xps and rde results, they concluded that the. The synthesis of nitrogendoped multiwalled carbon nanotubes using an fecocaco 3 catalyst z. Sample purity is documented with sem, tem, electron microprobe analysis, raman, and uv.

Synthesis and characterization of nitrogendoped carbon. The ac produced after the two activation steps showed a surface area as high as 833 m2 g. We demonstrate the waterassisted supergrowth of vertically aligned singlewalled carbon nitrogen nanotubes swnnts using a simple liquidgasphase precursor system. Atomic configuration of nitrogendoped singlewalled. Although similar in structure, carbon nanotubes in particular singlewalled cnts and graphene have different catalytic properties that are mostly due to the curvature of the cnts. Submitted in fulfillment of the academic requirements for the degree of doctor of philosophy. Xps analysis shows that the n 1s core level spectra for n. This interpretation is in concordance with the increase of the hardness observed by afm nanoindentations when the sp 3 contributions increase.

Nitrogendoped carbon nanotubes coated by atomic layer deposited sno 2 with controlled morphology and phase xiangbo meng, yu zhong, yifan sun, mohammad norouzi banis, ruying li, xueliang sun. Surface modification of nitrogendoped carbon nanotubes by. The present work focuses on nitrogendoped, defectinduced surfacemodified carbon nanotubes mnbcnt having the synergy of both the effects to improve the electrochemical performance of the nib. Oct 22, 2019 the nitrogen doped carbon shell with the fast electron diffusion ability and the electrocatalytic behaviors of the lewis base matrix can provide more active sites for trapping polysulfides, which. Xray photoelectron spectroscopy of graphitic carbon. For comparison, the doped tubes were grown as a function of temperature using melamine and pyridine as different nitrogen sources. A purification method has been developed that provides for the removal of metal catalysts and impurity carbon from laserovengrown singlewall carbon nanotube swnt material. The present work describes the synthesis of nitrogen doped multiwalled carbon nanotubes cnx cnt. Nitrogen doped carbon nanotubes from organometallic. Nitrogendoped carbon nanotubes coated by atomic layer. Purification and characterization of singlewall carbon. Nitrogendoped carbon nanotubes ncnts can be produced through five main methods. In this work, we report a simple but effective strategy to synthesize rich nitrogendoped carbon on carbon nanotubes nemail protected which possesses large surface area with a large number of mesopores and micropores. Different acs were synthesised via two activation steps.

Spaceconfined synthesis of threedimensional boronnitrogen. A series of various experiments were performed, using different proportions of the reaction mixture, in order to optimize the production conditions of. Although nitrogendoped carbon nanotubes are a very poor hydrogen oxidation catalyst, as a support, it increases the catalytic performance of nickel nanoparticles by a. Xps protocol for the characterization of pristine and. Influence of oxygen on nitrogendoped carbon nanofiber growth. Femn nanoparticles encapsulated in nitrogendoped carbon. A fluorescent sensor constructed from nitrogendoped carbon nanodots ncds for ph detection in synovial fluid and urea determination.

Characterization of fluorinated multiwalled and single. Nitrogendoped carbon nanofibers as an highly efficient. Characterization of nitrogendoped carbon nanotubes by atomic force microscopy, xray photoelectron spectroscopy and xray absorption near edge spectroscopy. It is easy to confuse only on the basis of sem observations carbon nanotubes from. The fluorine percentages of fluorinated multiwalled carbon nanotubes fmwcnts and fluorinated singlewalled carbon nanotubes fswcnts were. Xps characterization of nitrogenadoped carbon nanotubes. Nitrogen doped carbon nanotubes ncnts have become a topic of increased importance in the study of carbonaceous materials.

Xps analysis shows that the n 1s core level spectra for ndoped cnts can be. Organic solar cells with boron or nitrogendoped carbon. Templateguided synthesis of co nanoparticles embedded in. Jan 29, 20 the typical bamboolike nitrogen doped carbon nanotubes ncnts have been successfully synthesized via pyrolysis of melamine c 3 n 6 h 6. Nitrogendoped carbon spongetype nanostructures ncstns containing coaxial multiwalled carbon nanotubes are synthesized at 1020 c by using a modified chemical.

Supplementary information oxidation nitrogendoped carbon. Pinetreelike morphologies of nitrogendoped carbon nanotubes. With the data at hand, it is interesting to note that in the xps spectra of nitrogendoped carbon nanotubes, regardless of the synthesis method there always seems to be at best an approximately equal ratio of binding energy components attributed to pyridinic and graphitic nitrogen, especially in singlewalled tubes 115,117,120,124,3. The chosen production method was the catalytic pyrolysis of a solid mixture containing nidmg2 and melamine c3h6n6, under an. Abstract in this work, cnts have been bombarded with low energy n ions.

Research article synthesis and characterization of silver nanoparticlemultiwalled carbon nanotube composites dunieskysg. Metalfree and electrocatalytically active nitrogendoped carbon nanotubes synthesized by coating with polyaniline. Atomic configuration of nitrogendoped singlewalled carbon nanotubes raul arenal1,2, katia march 3, chris p. Zif67 nanocrystals are insitu loaded on the surface of ppy nanotubes which serve as the skeleton and nitrogen source, in which the sodium laurylsulfonate endows ppy. Herein, we developed co nanoparticles embedded in hollow nitrogen doped carbon tubes email protected to act as highly efficient and durable electrocatalyst for orr and oer. View enhanced pdf access article on wiley online library html view. Xps and fesemstem surface characterization of activated carbon, carbon black, and carbon nanotubes author br strohmeier, jd piasecki, kl bunker, jl sturgeon, ba stitch, jp marquis. Synthesis of nitrogendoped carbon nanotubes with layered double hydroxides containing iron, cobalt or nickel as catalyst precursors yong caoa,b, qingze jiaob, yun zhaob, gangfu song aand peiyong zhang ainstitute of environment and municipal engineering, north china institute of water conservancy and hydroelectric power, zhengzhou 450011, peoples republic of china. Xray photoelectron spectroscopic characterization of. Considering the high carbon and nitrogen solubility in ni and cr, respectively, we explore the growth of ndoped carbon nanostructures on the metal alloy substrate. The morphology of the samples is characterized by field emission scanning electron microscopy fesem and transmission electron microscopy tem. In spite of the fact that sem analysis gives valuable information in morphological and structural characterization of cnts, it is however not sufficient to establish the ultimate nature of carbon nanotubes. Electron field emission enhancement volume 29 issue 20 maria luisa garciabetancourt, nestor perealopez, sofia m.